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Hi @exigomedia,
You can certainly display custom fields on the PDF invoices from the order data, but it is not something that work out of the box. Take into account that WooCommerce stores a lot of details within the order data, and we cannot just simply display all of them automatically.
That said, there are different ways to achieve it, whether using the customizer included in Premium Templates, or with a code snippet, using the PDF template action hooks. Also, you could try by creating a custom template, but I do not recommend this method, if you just need to display a single custom field.
Please check this article out to learn more: Displaying a custom field.