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Our plugin uses AppScripts code to sync data with Google Sheets. You can’t manually add a new column in the connected Google sheet. Instead, you can keep the note as a new column by WooCommerce Custom Order Field which is supported by WooCommerce, and our plugin can sync it that way.
We would like to inform you that WooCommerce Custom Order Fields is a feature of our premium plugin.
According to the forum guidelines, support for commercial products is not permitted in the forums. To get support for the premium version of our plugin, kindly contact us through our official support channel.
Have a nice day!