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Captcha Code uses $_SESSION to store it’s captcha challenge so there might be a conflict with another plugin if they also call session_start at some different point. Unfortunately issues like this are really hard/impossible to figure out without access to the server so I really can’t do anything other than suggest that you use a different plugin for captcha. We have another plugin, https://projectdmc.org/plugins/advanced-google-recaptcha/ that does not use sessions so that might work out better 🙂