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Hi @lottemocha,
Yes, this is possible with the Order Notification included in the Professional extension. This notification allows you to send PDF documents copy to another email address(es), based in a trigger, e.g. when the order reaches the Completed status, which seems to be the right trigger for your case.
That said, since WordPress doesn’t allow us to provide support or answering pre-sale questions for paid plugins in this forum, please contact us by email at [email protected].