Hi @massidrink1976,
Yes, it is, but you would need the Premium Templates extension, includes in WooCommerce PDF Invoices and Packing Slips Bundle, to be able to use the customizer, which is a drag & drop builder that you can use to modify the structure of the PDF documents.
For instance, you can add the tax rate and VAT columns to the order list, as well as the product thumbnail, single and total price, etc.:
Since WordPress.org does not allow us to provide support for paid plugins, or answering pre-sale questions in this forum, please contact us by email to [email protected], if you have further questions.